高等学校化学学报 ›› 2004, Vol. 25 ›› Issue (4): 753.

• 研究论文 • 上一篇    下一篇

悬浮扩散共聚法制备聚合物GRIN小球及对折射率梯度分布的控制

夏茹1, 章于川1, 易佑民2, 董亮伟2, 石市委2   

  1. 1. 安徽大学化学化工学院,
    2. 物理系, 合肥 230039
  • 收稿日期:2003-02-08 出版日期:2004-04-24 发布日期:2004-04-24
  • 通讯作者: 章于川(1946年出生),男,教授,从事功能高分子材料研究.E-mail:zyc19461@mail.hf.ah.cn E-mail:zyc19461@mail.hf.ah.cn
  • 基金资助:

    安徽省教育厅自然科学基金重点项目(批准号:2002KJ029ZD)资助

Preparation of Polymer Spherical Symmetry GRIN Microsphereby SDC and Controlling Its Gradient Index Distribution

XIA Ru1, ZHANG Yu-Chuan1, YI You-Min2, DONG Liang-Wei2, SHI Shi-Wei2   

  1. 1. Department of Chemistry;
    2. Department of Physics, Anhui University, Hefei 230039, China
  • Received:2003-02-08 Online:2004-04-24 Published:2004-04-24

摘要: 选用MMA为单体M1、3FEA为单体M2,通过悬浮扩散共聚法制备了可见光透过率为90%的聚合物GRIN小球.采用剪切干涉法测得小球内的折射率基本上呈抛物线型球对称梯度分布,折射率差Δn达到0.019.

关键词: 悬浮扩散共聚合, 小球透镜, 球对称梯度折射率分布, 剪切干涉法

Abstract: A polymer spherical GRIN sphere lens was prepared by the suspension-diffusion-copolymerization(SDC) technique by using MMA as monomer M1 and 3FEA as M2. The radial distribution of refractive index of the lens was measured by the shearing interference method, which demonstrated that the quadratic refractive-index distribution was formed in the sphere lens, and its Δn=0.019.

Key words: Suspension-diffusion-copolymerization(SDC), Microsphere lens, Spherical symmetry gradient index distribution, Shearing interferometric technique

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