高等学校化学学报

高等学校化学学报 ›› 2004, Vol. 25 ›› Issue (3): 592.

• 研究简报 • 上一篇    

母体苯胺六聚体的一步法合成及紫外光谱研究

陈梁, 于有海, 毛华平, 卢晓峰, 张万金   

  1. 吉林大学麦克德尔米德实验室, 长春 130012
  • 收稿日期:2003-04-14 出版日期:2004-03-24 发布日期:2004-03-24
  • 通讯作者: 张万金(1954年出生),男,博士,教授,博士生导师,主要从事有机纳米功能材料和特种工程塑料的合成及应用研究.E-mail;W jzhang@jlu.edu.cn E-mail:W jzhang@jlu.edu.cn
  • 基金资助:

    国家“九七三”计划项目(批准号;001CB610505);重大国际合作项目(批准号;20320120169)资助

Synthesis of Parent Aniline Hexamer via One-step Method and Its UV-Vis Spectral Study

CHEN Liang, YU You-Hai, MAO Hua-Ping, LU Xiao-Feng, ZHANG Wan-Jin   

  1. Alan G. MacDiarmid Institute, Jilin University, Changchun 130012, China
  • Received:2003-04-14 Online:2004-03-24 Published:2004-03-24

PDF (PC)

被引次数

5

关键词: 氧化偶联反应, 聚苯胺, 母体苯胺六聚体

Abstract: The parent aniline hexamer was synthesized in the emeraldine base(EB) oxidation state through one step oxidative coupling reaction using parent aniline trimer in the leucoemeraldine oxidation state. The hexamer in the EB state was reduced by phenylhydrazine in ethanol and was characterized by IR, 1H NMR , MALDI-TOF-MS and elemental analysis. The chemical oxidation process of the hexamer was studied by UV-Vis spectra. It was found that the hexamer was oxidized to its EB form and then to the pernigraniline oxidation state.

Key words: Oxidative coupling reaction, Polyaniline, Parent aniline hexamer

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