银盘电极交流示波计时电位法及其机理的研究

高等学校化学学报 ›› 2002, Vol. 23 ›› Issue (3): 379.

银盘电极交流示波计时电位法及其机理的研究

于科岐¹, 董社英^1,2, 汤宏胜¹, 高鸿¹

1. 西北大学分析科学研究所, 西安 710069;
2. 长治医学院化学教研室, 长治 046000

收稿日期:2000-11-28 出版日期:2002-03-24 发布日期:2002-03-24
通讯作者: 于科岐(1964年出生),男,博士,主要从事电分析化学和化学计量学研究.
基金资助:
国家自然科学基金(批准号:29775018);西北大学科学研究启动基金资助

The Investigation of Oscillographic Chronopotentiometry at Silver Disk Electrode and Its Mechanism

YU Ke-Qi¹, DONG She-Ying^1,2, TANG Hong-Sheng¹, GAO Hong¹

1. Institute of Analytical Science, Northwest University, Xi'an 710069, China;
2. Section of Chemistry, Changzhi Medical College, Changzhi 046000, China

Received:2000-11-28 Online:2002-03-24 Published:2002-03-24

摘要/Abstract

关键词: 银盘电极, 示波测定, 交流示波计时电位法

Abstract: A new method of oscillographic chronopotentiometry at silver disk electrode for the determination was initially investigated and established. By using it, we determined a series of ions. The detection limits were decreased two or three orders of magnitude of that for the oscillographic chronopotentiometry at mercury electrode. This method was characterized by fine sensitivity, stable oscillogram and was not used for mercury. The research on mechanism of this method showed that these achievements were caused by the characteristics of silver electrooxidation and electroreduction and the A.C. oscillographic chronopotentiometry(ACOC).

Key words: Silver disk electrode, Oscillographic determination, Oscillographic chronopotentiometry

中图分类号:

O657.14

TrendMD:

于科岐, 董社英, 汤宏胜, 高鸿. 银盘电极交流示波计时电位法及其机理的研究. 高等学校化学学报, 2002, 23(3): 379.

YU Ke-Qi, DONG She-Ying, TANG Hong-Sheng, GAO Hong . The Investigation of Oscillographic Chronopotentiometry at Silver Disk Electrode and Its Mechanism. Chem. J. Chinese Universities, 2002, 23(3): 379.