高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (S1): 443.
• Synthetic Sciences • 上一篇 下一篇
LIU Ying1, DOU Tian-Min1, ZHANG Rong-Lan1, DAI Ji-Cui1, LI Xue2, ZHENG Pei-Ju2
LIU Ying1, DOU Tian-Min1, ZHANG Rong-Lan1, DAI Ji-Cui1, LI Xue2, ZHENG Pei-Ju2
摘要:
The cation-π interactions have attracted much attention as an important noncovalent binding force. We have synthesized and characterized the first example[K(DB 18C6)]2[Pd(SCN)4] which exist K+-π interactions in crown ether compounds[1]. However,the reported Na+ complexes structurally characterized by X-ray diffraction analysis have so far been limited to a few compounds. We now report the structure of complex:[Na(DB18C6)]2[Pd(SCN)4] which also exist Na+-n interactions.
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