高等学校化学学报

高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (S1): 442.

• Synthetic Sciences • 上一篇    下一篇

Nickel-Catalyzed Hydroesterification of Acetylene with Methyl Formate to Methyl Acrylate in Fixed Bed

HUANG Xin-Han, YANG Xian-Gui, ZHANG Jia-Qi, LIU Zhao-Tie   

  1. Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041
  • 出版日期:2000-12-31 发布日期:2000-12-31
  • 通讯作者: LIU Zhao-Tie E-mail:ioclzt@mail.sc.cninfo.net
  • 基金资助:

    Project 29703008 Supported by NSFC.

Nickel-Catalyzed Hydroesterification of Acetylene with Methyl Formate to Methyl Acrylate in Fixed Bed

HUANG Xin-Han, YANG Xian-Gui, ZHANG Jia-Qi, LIU Zhao-Tie   

  1. Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041
  • Online:2000-12-31 Published:2000-12-31
  • Contact: LIU Zhao-Tie E-mail:ioclzt@mail.sc.cninfo.net
  • Supported by:

    Project 29703008 Supported by NSFC.

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被引次数

1

摘要：

The hydroesterification of acetylene with methyl formate catalyzed by nickel-supported catalysts without any corrosive halide promoter has been comprehensively studied in a fixed bed reactor under various conditions. This reaction can be particularly useful since methyl formate may act as a source of methanol-carbon monoxide, thus simplifying transport and handling[1-3]. The catalysts were prepared by wet impregnation of γ-Al2O3 support with NiCl2 aqueous solution, then dried at 120℃ and calcined at 500℃

Abstract:

The hydroesterification of acetylene with methyl formate catalyzed by nickel-supported catalysts without any corrosive halide promoter has been comprehensively studied in a fixed bed reactor under various conditions. This reaction can be particularly useful since methyl formate may act as a source of methanol-carbon monoxide, thus simplifying transport and handling[1-3]. The catalysts were prepared by wet impregnation of γ-Al2O3 support with NiCl2 aqueous solution, then dried at 120℃ and calcined at 500℃

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