高等学校化学学报

高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (S1): 441.

• Synthetic Sciences • 上一篇    下一篇

Photopromoted Carbonylation of Olefins with Carbon Dioxide by Transition Metal Complexes Catalysis

YIN Jing-Mei1, GAO Da-Bin1, YU Ye-Cheng1, ZHENG Xue-Fang1, GUO Ming1, GU Yang2, WANG Xiang-Sheng2, GUO Xin-Wen2   

  1. 1. Department of Chemistry & Chemical Engineering, Dalian University, Dalian 116622;
    2. Open Laboratory of Carbon Resource Utilization, Dalian University of Technology, Dalian 116012
  • 出版日期:2000-12-31 发布日期:2000-12-31
  • 通讯作者: GAO Da-Bin

Photopromoted Carbonylation of Olefins with Carbon Dioxide by Transition Metal Complexes Catalysis

YIN Jing-Mei1, GAO Da-Bin1, YU Ye-Cheng1, ZHENG Xue-Fang1, GUO Ming1, GU Yang2, WANG Xiang-Sheng2, GUO Xin-Wen2   

  1. 1. Department of Chemistry & Chemical Engineering, Dalian University, Dalian 116622;
    2. Open Laboratory of Carbon Resource Utilization, Dalian University of Technology, Dalian 116012
  • Online:2000-12-31 Published:2000-12-31
  • Contact: GAO Da-Bin

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摘要：

The carbonylation of olefins is important and essential methods to synthesize organic compounds,Which requires high temperature (150-200℃) and high pressure (10~20MPa) in addition to precious metal complex catalysts (such as Ru,Rh, Ir)[1], In recent years photopromoted organic syntheses have received more and more attentions that were called environmentally friendly technique because of their ambient reaction conditions,high reactivities and selectivities and a little pollution[2]. Photopromoted carbonylation can be completed in ambient conditions and by non-precious complexes catalysts, and especially photopromoted methoxycarbonylation of olefins could give better results[3,4]. In previous papers we have established that the methoxycarbonylation of olefins with carbon dioxide could be carried out in place of carbon monoxide.

Abstract:

The carbonylation of olefins is important and essential methods to synthesize organic compounds,Which requires high temperature (150-200℃) and high pressure (10~20MPa) in addition to precious metal complex catalysts (such as Ru,Rh, Ir)[1], In recent years photopromoted organic syntheses have received more and more attentions that were called environmentally friendly technique because of their ambient reaction conditions,high reactivities and selectivities and a little pollution[2]. Photopromoted carbonylation can be completed in ambient conditions and by non-precious complexes catalysts, and especially photopromoted methoxycarbonylation of olefins could give better results[3,4]. In previous papers we have established that the methoxycarbonylation of olefins with carbon dioxide could be carried out in place of carbon monoxide.

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