高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (6): 941.

• 综合评述 • 上一篇    下一篇

温控相转移催化——水/有机两相催化新进展

金子林, 梅建庭, 蒋景阳   

  1. 大连理工大学精细化工国家重点实验室, 大连 116012
  • 收稿日期:1999-09-10 出版日期:2000-06-24 发布日期:2000-06-24
  • 通讯作者: 金子林(1936年生),男,教授,博士导师.从事精细有机合成及络合催化研究.E-mail:jingyan@mail.dlptt.ln.cn E-mail:jingyan@mail.dlptt.ln.cn
  • 基金资助:

    国家自然科学基金(批准号:29792074);中国石化总公司联合资助重大项目资助

Thermoregulated Phase-transfer Catalysis ——Recent Advances in Water/Organic Biphasic Catalysis

JIN Zi-Lin, MEI Jian-Ting, JIANG Jing-Yang   

  1. State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, China
  • Received:1999-09-10 Online:2000-06-24 Published:2000-06-24

摘要: 综述了“温控相转移催化”的原理,温控膦配体的设计、合成及其在水溶性极小的底物高碳烯烃的水/有机两相氢甲酰化反应中的应用效果.

关键词: 水溶性膦配体, 温控相转移催化, 水/有机两相氢甲酰化, 均相催化剂分离

Abstract: Water/organic biphasic catalysis provided a kind effective way for solving the problem of difficulty from recovering the catalyst in homogeneous catalysis theoretically and practically. So far its application range has been seriously restricted by the water solubility of the substrates. Such a restriction will be fundamentally eliminated by thermoregulated phase-transfer catalysis. The principle of the thermoregulated phase-transfer catalysis, the design and synthesis of thermoregulated phase-transfer ligands and their application in the water/organic two phase-hydroformylation of higher olefins severally insoluble in water, were systematically introduced.

Key words: Water-soluble phosphiino ligands, Thermoregulated phase-transfer catalysis, Water/organic two-phase hydroformylation, Homogeneous catalysts separation

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