高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (3): 377.

• 研究快报 • 上一篇    下一篇

超痕量H2O2对MnSO4-KBrO3-乙酰丙酮化学振荡体系的扰动

张珂, 蔡汝秀, 马万红, 林智信, 甘南琴   

  1. 武汉大学化学与环境科学学院, 武汉 430072
  • 收稿日期:1999-07-26 出版日期:2000-03-24 发布日期:2000-03-24
  • 通讯作者: 蔡汝秀(1939年出生),女,教授,博士生导师,主要从事分子光谱与分析化学动力学研究.
  • 基金资助:

    国家自然科学基金(批准号:29775015)

Perturbation Effect of Ultra Trace Hydrogen Peroxide on the MnSO4-KBrO3-Diacetone Oscillating Chemical Reaction

ZHANG Ke, CAI Ru-Xiu, MA Wan-Hong, LIN Zhi-Xin, GAN Nan-Qin   

  1. Department of Chemistry, Wuhan University, Wuhan 430072, China
  • Received:1999-07-26 Online:2000-03-24 Published:2000-03-24

关键词: 化学振荡反应, H2O2, 连续流动搅拌反应器(CSTR), 非线性动力学

Abstract: The similarities between life processes that exhibit oscillatory behavior and chemical oscillating systems impel people to think that the biological and abiological phenomena conform to the same law. Oscillating chemical systems have been the focus of much research in the area of theoretical and experimental chemical dynamics as well as analytical sciences in recent years, but the studies on the perturbation species are kept around the concentration level of 10-7 mol/L. In our experiment, an amazed phenomenon was found. Ultra trace level (10-20 mol/L) of H2O2 can cause so magnitude influence on the macro system (MnSO4-KBrO3-diacetone oscillating chemical system) that the effect can be observed by a macroscopical method. When the concentration of H2O2 is above 10-13mol/L , the oscillation can even be stopped. Afurther study on the mechanism will doubtlessly help to understand the mystery of life, such as the sudden cardiopathy and the metabolism failure.

Key words: Oscillating chemical reaction, Hydrogen peroxide, CSTR(continuous-flow stirred tank reactor), Nonlinear kinetics

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