高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (11): 1675.

• 论文 • 上一篇    下一篇

三对节中两个新环烯醚萜甙的研究

魏小梅, 朱启秀, 陈锦春, 程东亮   

  1. 兰州大学化学系, 应用有机化学国家重点实验室, 兰州 730000
  • 收稿日期:1999-10-19 出版日期:2000-11-24 发布日期:2000-11-24
  • 通讯作者: 程东亮(1935年出生),男,教授,博士生导师,主要从事天然产物化学研究.
  • 基金资助:

    国家自然科学基金(批准号:29772010)资助

Two New Iridoid Glucosides from Clerodenrum Serratum

WEI Xiao-Mei, ZHU Qi-Xiu, CHEN Jin-Chun, CHENG Dong-Liang    

  1. Department of Chemistry, National Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China
  • Received:1999-10-19 Online:2000-11-24 Published:2000-11-24

摘要: 从三对节的叶子中分离得到4个化合物,经化学和光谱方法鉴定其为7-O-p-Coumaroyloxyugandoside(1),7-O-cinnamoyloxyugandoside(2),acteoside(3)和martynoside(4).其中前两者是新环烯醚萜甙化合物,后两者为首次从该植物中获得的苯丙素甙类化合物.

关键词: 三对节, 马鞭草科, 赪桐属, 环烯醚萜甙, 苯丙素甙, 2DNMR谱

Abstract: Four compounds were obtained from the leaves of Clerodendrum serratum. By means of spectroscopic techniques(such as IR, UV, MS, 1H NMR , 13C NMR and 2D-NMR) and chemical evidences, their structures were elucidated as 7-O-p-coumaroyloxyugandoside(1), 7-O-cinnamoyloxyugandoside(2), acteoside(3) and martynoside(4) respectively. Compounds 1 and 2 were new iridoid glucosides, compunds 3 and 4 were phenylpropanoid glycosides which were obtained for the first time from this plant.

Key words: Clerodendrum serratum, Verbenaceae, Clerodenrum, Iridoid glucoside, Phenylpropanoid glycoside, 2D-NMR

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