高等学校化学学报 ›› 1999, Vol. 20 ›› Issue (S1): 66.

• Atomic Spectrometry • 上一篇    下一篇

Capillary Electrophoresis Coupled On-Line with Inductively Coupled Plasma Atomic Emission Spectrometry for Elemental Speciation

DENG Bi-Yang, Chan Flora Y. Y., Choi Anton K. H., CHAN Wing-Tat   

  1. Department of Chemistry, The University of Hong Kong, Pohfulam Road, Hong Kong
  • 出版日期:1999-12-31 发布日期:1999-12-31

Capillary Electrophoresis Coupled On-Line with Inductively Coupled Plasma Atomic Emission Spectrometry for Elemental Speciation

DENG Bi-Yang, Chan Flora Y. Y., Choi Anton K. H., CHAN Wing-Tat   

  1. Department of Chemistry, The University of Hong Kong, Pohfulam Road, Hong Kong
  • Online:1999-12-31 Published:1999-12-31

摘要:

Capillary electrophoresis (CE) has become a powerful analytical technique for the separation of a variety of analytes ranging from small inorganic ions to large biomolecules such as proteins and nucleic acids. A selective and sensitive detector for CE has been one of the most important and challenging prerequisites for the growth of CE. On-column UV-Vis detectors are commonly used to determine the analytes separated by CE. However, these detectors are often not very selective. Other detection techniques such as mass spectrometry, laser induced fluorescence, amperometry, and inductively coupled plasma spectrometry have been investigated to provide a more sensitive and selective detection for the target analytes. However, relatively few studies have been published on the use of inductively coupled plasma atomic emission spectrometry (ICP-AES) as a means of detection in CE separation.

Abstract:

Capillary electrophoresis (CE) has become a powerful analytical technique for the separation of a variety of analytes ranging from small inorganic ions to large biomolecules such as proteins and nucleic acids. A selective and sensitive detector for CE has been one of the most important and challenging prerequisites for the growth of CE. On-column UV-Vis detectors are commonly used to determine the analytes separated by CE. However, these detectors are often not very selective. Other detection techniques such as mass spectrometry, laser induced fluorescence, amperometry, and inductively coupled plasma spectrometry have been investigated to provide a more sensitive and selective detection for the target analytes. However, relatively few studies have been published on the use of inductively coupled plasma atomic emission spectrometry (ICP-AES) as a means of detection in CE separation.

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