高等学校化学学报

高等学校化学学报 ›› 1999, Vol. 20 ›› Issue (S1): 580.

• Teaching and Education in Analytical Chemistry;NMR;Others • 上一篇    下一篇

51V NMR for Monitoring[VS4-Cu2] Cluster Synthesis:Transient Kinetic Studies and Evaluation of a Putative Reaction Intermediate

YE Jian-Liang1, CHEN Zhong1, ZHENG Fa-Kun2, CHEN Zhi-Wei1, ZHOU Xing-Wang1, HUANG Jin-Shun2   

  1. 1. Department of Chemistry and the Key Laboratory of Analytical Sciences of MOE, Xiamen University, Xiamen 361005, P. R. China;
    2. Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science State Key Laboratory of Structure Chemistry, Fuzhou 35002, P. R. China
  • 出版日期:1999-12-31 发布日期:1999-12-31
  • 基金资助:

    Supported by NNSF of China (No. 19605004), State Key Laboratory of Structural Chemistry and the Key Lab. of Analytical Sciences of DOEC

51V NMR for Monitoring[VS4-Cu2] Cluster Synthesis:Transient Kinetic Studies and Evaluation of a Putative Reaction Intermediate

YE Jian-Liang1, CHEN Zhong1, ZHENG Fa-Kun2, CHEN Zhi-Wei1, ZHOU Xing-Wang1, HUANG Jin-Shun2   

  1. 1. Department of Chemistry and the Key Laboratory of Analytical Sciences of MOE, Xiamen University, Xiamen 361005, P. R. China;
    2. Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science State Key Laboratory of Structure Chemistry, Fuzhou 35002, P. R. China
  • Online:1999-12-31 Published:1999-12-31
  • Supported by:

    Supported by NNSF of China (No. 19605004), State Key Laboratory of Structural Chemistry and the Key Lab. of Analytical Sciences of DOEC

PDF (PC)

摘要：

[VS4-Cun] (n=l,2) cluster hasn't been synthesized due to the strong affinity between[VS4] and Cu. Therefore, synthesis of these complexes require new applications of nondestructive analytical tools to monitor the progress of reactions. Herein we describe 5lV NMR technique to validate the synthesis for[VS4-Cu2] cluster.

Abstract:

[VS4-Cun] (n=l,2) cluster hasn't been synthesized due to the strong affinity between[VS4] and Cu. Therefore, synthesis of these complexes require new applications of nondestructive analytical tools to monitor the progress of reactions. Herein we describe 5lV NMR technique to validate the synthesis for[VS4-Cu2] cluster.

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