高等学校化学学报

高等学校化学学报 ›› 1999, Vol. 20 ›› Issue (S1): 389.

• Molecular Spectroscopy • 上一篇    下一篇

Combining SERS and Electrochemical Transient Technique to Study Structural Change of Coadsorbed Species at Au electrodes

YAO Jian-Lin1, LIU Feng-Ming1, XIE Yong1, SHE Chun-Xing1, REN Bin1, TIAN Zhong-Qun1, CAO Pei-Gen2, GU Ren-Ao2   

  1. 1. State Key Laboratory for Physical Chemistry of Solid Surfaces, Institute of Physical Chemistry and Department of Chemistry, Xiamen University, Xiamen 361005, P. R. China;
    2. Department of Chemistry, Suzhou University, Suzhou 215006, P. R. China
  • 出版日期:1999-12-31 发布日期:1999-12-31
  • 基金资助:

    Supported by the Natural Science Foundation of China.

Combining SERS and Electrochemical Transient Technique to Study Structural Change of Coadsorbed Species at Au electrodes

YAO Jian-Lin1, LIU Feng-Ming1, XIE Yong1, SHE Chun-Xing1, REN Bin1, TIAN Zhong-Qun1, CAO Pei-Gen2, GU Ren-Ao2   

  1. 1. State Key Laboratory for Physical Chemistry of Solid Surfaces, Institute of Physical Chemistry and Department of Chemistry, Xiamen University, Xiamen 361005, P. R. China;
    2. Department of Chemistry, Suzhou University, Suzhou 215006, P. R. China
  • Online:1999-12-31 Published:1999-12-31
  • Supported by:

    Supported by the Natural Science Foundation of China.

PDF (PC)

摘要：

Although surface-enhanced Raman spectroscopy (SERS) is probably one of the most sensitive surface spectroscopic techniques, most of the previously electrochemical SERS studies have been carried out in steady state. Recently, much attention has been attracted to combine time-dependent SERS with electrochemical transient techniques to investigate the electrode/solution interfacial dynamics at molecular level[1,2]. Our previous studies indicate that thiourea (TU) can coadsorb with ClO4- at Au electrodes in steady state. In the present work, time-dependent SERS has been used to study the structural change with the potential step for the coadsorption system.

Abstract:

Although surface-enhanced Raman spectroscopy (SERS) is probably one of the most sensitive surface spectroscopic techniques, most of the previously electrochemical SERS studies have been carried out in steady state. Recently, much attention has been attracted to combine time-dependent SERS with electrochemical transient techniques to investigate the electrode/solution interfacial dynamics at molecular level[1,2]. Our previous studies indicate that thiourea (TU) can coadsorb with ClO4- at Au electrodes in steady state. In the present work, time-dependent SERS has been used to study the structural change with the potential step for the coadsorption system.

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