高等学校化学学报 ›› 1999, Vol. 20 ›› Issue (S1): 293.

• Chromatography and Separation Sciences • 上一篇    下一篇

Lower limit and Non-linearity of Calibration in the Determination of Cations by Ultralow Background Conductance Suppressed Ion Chromatography

Dong Soo Lee1, Bo Kyung Lee1, Kyu-Ja Whang2   

  1. 1. Department of Chemistry, Yonsei University, Seoul 120-749, Korea;
    2. Department of Mamfacturing Phamacy, Sookmyung Women's University, Seoul 140-132, Korea
  • 出版日期:1999-12-31 发布日期:1999-12-31

Lower limit and Non-linearity of Calibration in the Determination of Cations by Ultralow Background Conductance Suppressed Ion Chromatography

Dong Soo Lee1, Bo Kyung Lee1, Kyu-Ja Whang2   

  1. 1. Department of Chemistry, Yonsei University, Seoul 120-749, Korea;
    2. Department of Mamfacturing Phamacy, Sookmyung Women's University, Seoul 140-132, Korea
  • Online:1999-12-31 Published:1999-12-31

摘要:

Non-linear calibration is one major drawback of suppressed conductivity ion chromatography and thus, it has been subjected to intensive investigations over the last two decades. The investigations are mostly confined to anion chromatography using weak base eluents like carbonate because the extent of non-linearity is proportional to dissociation constant, Ka, of the suppressed eluate.

Abstract:

Non-linear calibration is one major drawback of suppressed conductivity ion chromatography and thus, it has been subjected to intensive investigations over the last two decades. The investigations are mostly confined to anion chromatography using weak base eluents like carbonate because the extent of non-linearity is proportional to dissociation constant, Ka, of the suppressed eluate.

TrendMD: