高等学校化学学报 ›› 1999, Vol. 20 ›› Issue (S1): 214.

• Chromatography and Separation Sciences • 上一篇    下一篇

Determination of Interfacial Reaction Parameters in Ion-Association Extraction by Total Reflection Induced Thermal Lens

Hirofumi Kawazumi1, Takeshi Kaieda1, Toshihiro Ueha1, Teiichiro Ogawa2   

  1. 1. Kyushu School of Engineering, Kinki University, lizuka 820-8555, Japan;
    2. Graduate School of Engineering Sciences, Kyushu University, Kasuga, 816-8580, Japan
  • 出版日期:1999-12-31 发布日期:1999-12-31

Determination of Interfacial Reaction Parameters in Ion-Association Extraction by Total Reflection Induced Thermal Lens

Hirofumi Kawazumi1, Takeshi Kaieda1, Toshihiro Ueha1, Teiichiro Ogawa2   

  1. 1. Kyushu School of Engineering, Kinki University, lizuka 820-8555, Japan;
    2. Graduate School of Engineering Sciences, Kyushu University, Kasuga, 816-8580, Japan
  • Online:1999-12-31 Published:1999-12-31

摘要:

Studies on adsorption kinetics and reaction mechanism at liquid-liquid interfaces are very important for not only classical solvent extraction analysis but also modern nano-science. For this purpose, we should develop versatile techniques that have in-situ, real time and highly sensitive feature. An interfacial thermal lens (TL) technique has been developed for monitoring the formation of Fe(Ⅱ)-4,7-diphenyl-1,10-phenanthroline (DPP) complex at a benzene-acetate buffer interface.

Abstract:

Studies on adsorption kinetics and reaction mechanism at liquid-liquid interfaces are very important for not only classical solvent extraction analysis but also modern nano-science. For this purpose, we should develop versatile techniques that have in-situ, real time and highly sensitive feature. An interfacial thermal lens (TL) technique has been developed for monitoring the formation of Fe(Ⅱ)-4,7-diphenyl-1,10-phenanthroline (DPP) complex at a benzene-acetate buffer interface.

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