高等学校化学学报 ›› 1999, Vol. 20 ›› Issue (S1): 147.

• Electroanalytical Chemistry • 上一篇    下一篇

Synthesis and Fluorescence of a New Active Material for Electrochemiluminescent Sensor:Ru(phen)2[phen-NHCO(CH2)4Br](PF6)2

SHU Huo-Ming1, WANG Peng2, TIAN Fa-Ming2, ZHU Guo-Yi2   

  1. 1. Department of Chemistry, Hainan Normal University, Haikou 571158, P. R. China;
    2. Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China
  • 出版日期:1999-12-31 发布日期:1999-12-31

Synthesis and Fluorescence of a New Active Material for Electrochemiluminescent Sensor:Ru(phen)2[phen-NHCO(CH2)4Br](PF6)2

SHU Huo-Ming1, WANG Peng2, TIAN Fa-Ming2, ZHU Guo-Yi2   

  1. 1. Department of Chemistry, Hainan Normal University, Haikou 571158, P. R. China;
    2. Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China
  • Online:1999-12-31 Published:1999-12-31

摘要:

Recently, much attention has been paid to Ru(II) complexes because of their excellent properties of photochemistry, phtophysis. Bis(2,2'-bipyridine)[4-methyl-4'-(6-bromohexyl)-2,2'-bipyridine] ruthenium(II) perchlorate has been used as an active material for electrochemiluminescent (ECL) sensor for selective detection of oxalic acid.It is known that ECL efficiency of Ru(phen)32+ is much higher than that of Ru(bpy)32+. In order to make out more efficient ECL sensor, we have designed and synthesized a new Ru(II) complex, Ru(phen)2[phen-NHCO(CH2)4Br](PF6)2.

Abstract:

Recently, much attention has been paid to Ru(II) complexes because of their excellent properties of photochemistry, phtophysis. Bis(2,2'-bipyridine)[4-methyl-4'-(6-bromohexyl)-2,2'-bipyridine] ruthenium(II) perchlorate has been used as an active material for electrochemiluminescent (ECL) sensor for selective detection of oxalic acid.It is known that ECL efficiency of Ru(phen)32+ is much higher than that of Ru(bpy)32+. In order to make out more efficient ECL sensor, we have designed and synthesized a new Ru(II) complex, Ru(phen)2[phen-NHCO(CH2)4Br](PF6)2.

TrendMD: