高等学校化学学报 ›› 1999, Vol. 20 ›› Issue (S1): 147.
• Electroanalytical Chemistry • 上一篇 下一篇
SHU Huo-Ming1, WANG Peng2, TIAN Fa-Ming2, ZHU Guo-Yi2
SHU Huo-Ming1, WANG Peng2, TIAN Fa-Ming2, ZHU Guo-Yi2
摘要:
Recently, much attention has been paid to Ru(II) complexes because of their excellent properties of photochemistry, phtophysis. Bis(2,2'-bipyridine)[4-methyl-4'-(6-bromohexyl)-2,2'-bipyridine] ruthenium(II) perchlorate has been used as an active material for electrochemiluminescent (ECL) sensor for selective detection of oxalic acid.It is known that ECL efficiency of Ru(phen)32+ is much higher than that of Ru(bpy)32+. In order to make out more efficient ECL sensor, we have designed and synthesized a new Ru(II) complex, Ru(phen)2[phen-NHCO(CH2)4Br](PF6)2.
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