高等学校化学学报 ›› 1999, Vol. 20 ›› Issue (S1): 126.

• Electroanalytical Chemistry • 上一篇    下一篇

Potentiometric Titration of Some Sulphide Forming Ions by Dithiopyrilmethane

Petrov B. I.. Scherbakova L. V., Chebotarev V. K., Iljina Ye. G., Galkina I. V., Skirdova N. I., Nevskaya N. V.   

  1. Chemical Faculty, Altai State University, Barnaul, 656099, Russia
  • 出版日期:1999-12-31 发布日期:1999-12-31

Potentiometric Titration of Some Sulphide Forming Ions by Dithiopyrilmethane

Petrov B. I.. Scherbakova L. V., Chebotarev V. K., Iljina Ye. G., Galkina I. V., Skirdova N. I., Nevskaya N. V.   

  1. Chemical Faculty, Altai State University, Barnaul, 656099, Russia
  • Online:1999-12-31 Published:1999-12-31

摘要:

Dithiopyrilmethane (DTPM) is the sulphur containing derivative of pyrazolone. This reagent forms active mono- or biprotonated form giving stable, often colored complexes with sulphide forming metal ions. It is the most common that the reagent as a bidentate neutral ligand exists in these complexes giving cation or neutral complexes. This reagent is used in spectrophotometric and extractive spectrophotometric methods of analysis of sulphide forming metal ions.

Abstract:

Dithiopyrilmethane (DTPM) is the sulphur containing derivative of pyrazolone. This reagent forms active mono- or biprotonated form giving stable, often colored complexes with sulphide forming metal ions. It is the most common that the reagent as a bidentate neutral ligand exists in these complexes giving cation or neutral complexes. This reagent is used in spectrophotometric and extractive spectrophotometric methods of analysis of sulphide forming metal ions.

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