高等学校化学学报

高等学校化学学报 ›› 1999, Vol. 20 ›› Issue (S1): 125.

• Electroanalytical Chemistry • 上一篇    下一篇

The Electrochemistry of Viologens with Various Alkyl Substituents and The Dimerization of Their 1e- Reduced Species in the Absence and Presence of Various Cyclodextrins

Chongmok Lee1, Joon Woo Park1, II Cheol Jeon2   

  1. 1. Department of Chemistry, Ewha Womans University, Seoul 120-750, Korea;
    2. Department of Chemistry, Jeonbuk National University, Jeonbuk 561-756, Korea
  • 出版日期:1999-12-31 发布日期:1999-12-31
  • 基金资助:

    The support of this research by KOSEF 96-0531-05-01-3 and BSRl-90's~3427 is greatly acknowledged.

The Electrochemistry of Viologens with Various Alkyl Substituents and The Dimerization of Their 1e- Reduced Species in the Absence and Presence of Various Cyclodextrins

Chongmok Lee1, Joon Woo Park1, II Cheol Jeon2   

  1. 1. Department of Chemistry, Ewha Womans University, Seoul 120-750, Korea;
    2. Department of Chemistry, Jeonbuk National University, Jeonbuk 561-756, Korea
  • Online:1999-12-31 Published:1999-12-31
  • Supported by:

    The support of this research by KOSEF 96-0531-05-01-3 and BSRl-90's~3427 is greatly acknowledged.

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被引次数

7

摘要：

We present EQCM study for the electrochemical behavior of various 1-methyl-1'-alkylvilogen (C1CnV:n=1, 7-10, 12, 14,16, 18). In some viologens, we discussed the mechanism of CD-induced comproportionation reaction as well as electrodeposition pathway based on the EQCM and the spectroelectrochemical experimental results.

Abstract:

We present EQCM study for the electrochemical behavior of various 1-methyl-1'-alkylvilogen (C1CnV:n=1, 7-10, 12, 14,16, 18). In some viologens, we discussed the mechanism of CD-induced comproportionation reaction as well as electrodeposition pathway based on the EQCM and the spectroelectrochemical experimental results.

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