高等学校化学学报

高等学校化学学报 ›› 1999, Vol. 20 ›› Issue (7): 1031.

• 论文 • 上一篇    下一篇

反相胶束介质对2,3-二氨基吩嗪的荧光增敏作用研究

黄应平, 蔡汝秀, 黄厚评   

  1. 武汉大学化学系, 武汉 430072
  • 收稿日期:1998-09-28 出版日期:1999-07-24 发布日期:1999-07-24
  • 通讯作者: 蔡汝秀
  • 作者简介:黄应平,男,36岁,博士研究生.
  • 基金资助:

    国家自然科学基金(批准号:29775015);湖北省自然科学基金(批准号:97J226)资助课题

Studies on the Fluorescence Enhancement of Reverse Micelle on 2,3-Diaminophenazine

HUANG Ying-Ping, CAI RU Xiu, HUANG Hou-Ping   

  1. Department of Chemistry, Wuhan University, Wuhan, 430072
  • Received:1998-09-28 Online:1999-07-24 Published:1999-07-24

PDF (PC)

被引次数

20

摘要： 研究了反相胶束介质丁二酸双(2-乙基己基)酯磺酸钠(AOT)/正辛烷(n-octane)对漆酶催化氧化邻苯二胺的产物2,3-二氨基吩嗪(DAP)光谱性质的影响.试验表明,AOT/n-octane对DAP吸光性质稍有增敏作用,而对其荧光具有强烈的增敏作用,使DAP荧光量子产率提高近30倍,并进一步研究了微环境对荧光性质的影响和反相胶束介质AOT/n-octane对DAP荧光的增敏机理.

关键词: 反相胶束介质, 2.3－二氨基吩嗪, 荧光增敏, 分子光谱

Abstract: The effects of reverse micelle(AOT/n-octane) on spectral characteristics of 2,3-diaminophenazine (DAP), which was an oxidized product of o-phenylenediamine catalyzed by laccase, were investigated. It was shown that there was little effect on the absorption features of the product by AOT/n-octane. However the fluorescence of the product was greatly enhanced by AOT/n-octane, and the quantum yield was increased about 30-folds by AOT/n-octane. The effects of microenvironment on the fluorescent property of DAP and the mechanism of fluorescence enhancement in reverse micelle AOT/n-octane were also studied.

Key words: Reverse micelle, 2,3-Diaminophenazine, Fluorescence enhancement, Molecular spectrum

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