高等学校化学学报

高等学校化学学报 ›› 1999, Vol. 20 ›› Issue (4): 651.

• 论文 • 上一篇    下一篇

乙烯基单体/N-取代马来酰亚胺共聚合动力学

单国荣, 翁志学, 黄志明, 潘祖仁   

  1. 浙江大学化工系、高分子科学与工程研究所, 杭州 310027
  • 收稿日期:1998-08-24 出版日期:1999-04-24 发布日期:1999-04-24
  • 通讯作者: 单国荣,男,30岁,讲师,博士.
  • 作者简介:单国荣,男,30岁,讲师,博士.
  • 基金资助:

    教育部博士学科点专项科研基金(批准号:9533504)资助课题

Kinetics of Vinyl Monomer/N-Substituted Maleimide Copolymerization

SHAN Guo-Rong, WENG Zhi-Xue, HUANG Zhi-Ming, PAN Zu-Ren   

  1. Department of Chemical Engineering, Institute of Polymer Science and Engineering, Zhejiang University, Hangzhou, 310027
  • Received:1998-08-24 Online:1999-04-24 Published:1999-04-24

PDF (PC)

被引次数

66

摘要： 详细研究了聚合温度、引发剂用量、单体配比对苯乙烯(St)/N-苯基马来酰亚胺(PMI)共聚合动力学的影响.对St、甲基丙烯酸甲酯(MMA)和丙烯腈(AN)等单一或混合单体与PMI、N-环己基马来酰亚胺(ChMI)和N-邻氯苯基马来酰亚胺(o-CPMI)的共聚合进行了研究,并讨论了单体结构的影响.

关键词: 乙烯基单体, N－取代马来酰亚胺, 共聚合动力学

Abstract: The effects of reaction temperature, initiator concentration, and molar fraction of monomer on the copolymerization kinetics of styrene/N-phenylmaleimide were studied in detail. The copolymerizations of styrene, methyl methacrylate, acrylonitrile, or their mixtures with N-phenylmaleimide, N-cyclohexylmaleimide, or N-(o-chlorophenyl)maleimide were also investigated and discussed with the structure of comonomer pairs.

Key words: Vinyl monomer, N-Substituted maleimide, Kinetics of copolymerization

中图分类号: 

TrendMD: