高等学校化学学报

高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (S1): 312.

• Organic Synthesis Chemistry • 上一篇    下一篇

Mechanism of Reduction of 1,1-Dinitro-2,2-diphenylethylene by 1-Benzyl-1,4-dihydronicotinamide

Hong-Yi Wang1, Xiao-Qing Zhu3, You-Cheng Liu1,2, Shi-Dong Chu2, Qing-Xiang Guo2   

  1. 1. National Laboratory of Applied Organic Chemistry and Department of Chemistry, Lanzhou University, Lanzhou 730000;
    2. Department of Chemistry, University of Science and Technology of China, Hefei, 230026;
    3. Department of Chemistry, Nankai University, Tianjin 300071
  • 出版日期:1998-12-31 发布日期:1998-12-31
  • 通讯作者: You-Cheng Liu

Mechanism of Reduction of 1,1-Dinitro-2,2-diphenylethylene by 1-Benzyl-1,4-dihydronicotinamide

Hong-Yi Wang1, Xiao-Qing Zhu3, You-Cheng Liu1,2, Shi-Dong Chu2, Qing-Xiang Guo2   

  1. 1. National Laboratory of Applied Organic Chemistry and Department of Chemistry, Lanzhou University, Lanzhou 730000;
    2. Department of Chemistry, University of Science and Technology of China, Hefei, 230026;
    3. Department of Chemistry, Nankai University, Tianjin 300071
  • Online:1998-12-31 Published:1998-12-31
  • Contact: You-Cheng Liu

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摘要： 1-Benzyl-1,4-dihydronicotinamide (BNAH) is widely used as a model to mimic coenzyme NAD(P)H reductions1. The interest continues in distinguishing whether the formal hydride transfer from BNAH to the substrate takes place by a one-step hydride transfer or by an e-H+-e or e-H sequence2,3.

Abstract: 1-Benzyl-1,4-dihydronicotinamide (BNAH) is widely used as a model to mimic coenzyme NAD(P)H reductions1. The interest continues in distinguishing whether the formal hydride transfer from BNAH to the substrate takes place by a one-step hydride transfer or by an e-H+-e or e-H sequence2,3.

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