高等学校化学学报

高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (S1): 156.

• Organic Synthesis Chemistry • 上一篇    下一篇

First Total Synthesis of the (±)-Preverecynarmin

Jiong Lan1, Zuosheng Liu1, Yulin Li1, Wen Cen2, Yacheng Xing2   

  1. 1. National Laboratory of Applied Organic Chemistry and Institute of Organic Chemistry, Lanzhou University, Lanzhou 730000;
    2. Department of Chemistry, Qingdao University, Qingdao 266071
  • 出版日期:1998-12-31 发布日期:1998-12-31
  • 基金资助:
    This work was financially supported by the National Nature Science Foundation of China (Grant NO.29672015)

First Total Synthesis of the (±)-Preverecynarmin

Jiong Lan1, Zuosheng Liu1, Yulin Li1, Wen Cen2, Yacheng Xing2   

  1. 1. National Laboratory of Applied Organic Chemistry and Institute of Organic Chemistry, Lanzhou University, Lanzhou 730000;
    2. Department of Chemistry, Qingdao University, Qingdao 266071
  • Online:1998-12-31 Published:1998-12-31
  • Supported by:
    This work was financially supported by the National Nature Science Foundation of China (Grant NO.29672015)

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摘要： The preverecynarmin(12), (+)-(1E,3E,7E,11E)-cembra-3,7,11-tetraen-6yl acetate,was first isolated in 1990 from both Armina maculata and its prey,the pennatulacean coral Veretillum cynomorium with other there briarane diferpenoids and cembene-C((1E,3E,7E,11E)-cembra-l,3,7,11-tetraen1. As far as we known, the bioactive test and total synthesis of 12 have not been reported yet. Herein we wish to describe the first total synthesis of (±)-preverecynarmin (12).

Abstract: The preverecynarmin(12), (+)-(1E,3E,7E,11E)-cembra-3,7,11-tetraen-6yl acetate,was first isolated in 1990 from both Armina maculata and its prey,the pennatulacean coral Veretillum cynomorium with other there briarane diferpenoids and cembene-C((1E,3E,7E,11E)-cembra-l,3,7,11-tetraen1. As far as we known, the bioactive test and total synthesis of 12 have not been reported yet. Herein we wish to describe the first total synthesis of (±)-preverecynarmin (12).

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