高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (S1): 154.
• Organic Synthesis Chemistry • 上一篇 下一篇
Yacheng Xing1, Wen Cen1, Ying Li2, Jiong Lan2, Yulin Li2
Yacheng Xing1, Wen Cen1, Ying Li2, Jiong Lan2, Yulin Li2
摘要: (13S)-hydroxyneocembrene(18), a cembranoid which was isolated in 1988 from soft coral Sarcophyton trocheliophorum1, has been shown to be an effective inductor of the release of labeled glucose from the lecithincholesterol liposomes and have cytostatic activities2. The geometrical structure and absolute configuration of 18 have been defined to be 1S, 2E, 7E, 11E, 13S. Herein, we report the total synthesis of (±)-13hydroxyneocembrene(18).
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