无机/有机杂化IPN的合成与表征

高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (8): 1352.

无机/有机杂化IPN的合成与表征

王静媛, 秦东奇, 奚春宇, 于晓强, 李玉玮

吉林大学化学系, 长春, 130023

收稿日期:1997-07-10 出版日期:1998-08-24 发布日期:1998-08-24
通讯作者: 王静嫒,女,45岁,副教授.
作者简介:王静嫒,女,45岁,副教授.

Synthesis and Characterization of Hybrid Inorganic/Organic Interpenetrating Polymer Networks

WANG Jing-Yuan, QIN Dong-Qi, XI Chun-Yu, YU Xiao-Qiang, LI Yu-Wei

Department of Chemistry, Jilin University, Changchun, 130023

Received:1997-07-10 Online:1998-08-24 Published:1998-08-24

摘要/Abstract

摘要： 随着互穿聚合物网络(IPN)的发展,出现了无机/有机杂化IPN,调整两组分或多组分互穿程度控制材料的结构、形态与性能,可使材料具有较宽的适用范围.此类材料具有高模量、高韧性,易成型加工.

关键词: 分子筛13X, 聚甲基丙烯酸丁酯, 无机/有机杂化IPN

Abstract: A hybrid inorganic/organic interpenetrating polymer networks of a three-dimensional network structure zeolite 13X and crosslinked or linear polybutylmethacrylate was prepared in this paper. By changing the content of crosslinker and the composition ratio, the size of zeolite channels and the crosslinking density were controlled. The results of DSC, SEM, TBAand mechanical properties show that zeolite 13Xis an inorganic skeleton and some organic PBMArun through it, which makes the whole inorganic/organic IPNmaterial not only have the rigidity of inorganic substance but also have the toughness of organic substance. At the same time it improves the thermal stability of organic material.

Key words: Zeolite 13X, Poly(butyl methacrylate), Hybrid inorganic/organic IPN

中图分类号:

O631

TrendMD:

王静媛, 秦东奇, 奚春宇, 于晓强, 李玉玮. 无机/有机杂化IPN的合成与表征. 高等学校化学学报, 1998, 19(8): 1352.

WANG Jing-Yuan, QIN Dong-Qi, XI Chun-Yu, YU Xiao-Qiang, LI Yu-Wei. Synthesis and Characterization of Hybrid Inorganic/Organic Interpenetrating Polymer Networks. Chem. J. Chinese Universities, 1998, 19(8): 1352.

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