杯[4]芳烃涂层的TSM声波吡啶传感器的研究

高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (6): 882.

杯[4]芳烃涂层的TSM声波吡啶传感器的研究

曹忠, 黎彤, 羊小海, 王柯敏, 林辉概, 俞汝勤

湖南大学化学化工学院, 长沙, 410082

收稿日期:1997-08-13 出版日期:1998-06-24 发布日期:1998-06-24
通讯作者: 林辉概
作者简介:曹忠,男,29岁,博±,讲师,现在长沙电力学院化学系工作.
基金资助:
国家自然科学基金;国家教育委员会博±点基金

Studies on Thickness-shear-mode Acoustic Wave Pyridine Sensor Coated with Calix [4]arenes

CAO Zhong, LI Tong, YANG Xiao-Hai, WANG Ke-Min, LIN Hui-Gai, YU Ru-Qin

College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082

Received:1997-08-13 Online:1998-06-24 Published:1998-06-24

摘要/Abstract

关键词: 杯[4]芳烃, 主客识别, TSM声波传感器, 吡啶蒸气

Abstract: The frequency shift response characteristics for pyridine vapour by thickness shear-mode (TSM) acoustic wave sensors coated with three synthesized calix[4]arenes have been reported. It is shown that C-undecylcalix[4]resorcinarene(CUCRA) is the most efficient host-guest adsorptive material for sensing pyridine molecule. The CUCRA based TSM sensor possesses good reproducibility, high stability and short response time with a good linear determination range of 0.040～8.000 mg/Land a low detection limit down to 0.008 mg/Lof pyridine vapour while coating with 38 μg of CUCRA. The sensitivity is (54.63±2.35) Hz/(mg·L^-1)(n =5, 25℃). There are some interference from alcohols, amines, carboxylic acid, heterocyclic and aromatic compounds. Compared with gas chromatographic method, the sensor can be used for the determination of pyridine vapour with recovery rate of 98.10%-103.92%.

Key words: Calix[4] arene, Host-guest recognition, TSM acoustic wave sensor, Pyridine vapour

中图分类号:

O657

TrendMD:

曹忠, 黎彤, 羊小海, 王柯敏, 林辉概, 俞汝勤. 杯[4]芳烃涂层的TSM声波吡啶传感器的研究. 高等学校化学学报, 1998, 19(6): 882.

CAO Zhong, LI Tong, YANG Xiao-Hai, WANG Ke-Min, LIN Hui-Gai, YU Ru-Qin . Studies on Thickness-shear-mode Acoustic Wave Pyridine Sensor Coated with Calix [4]arenes. Chem. J. Chinese Universities, 1998, 19(6): 882.