高等学校化学学报

高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (5): 754.

• 研究快报 • 上一篇    下一篇

新的烯丙型环氧醇重排还原反应研究

涂永强, 王平珍, 陈耀祖   

  1. 兰州大学化学系, 应用有机化学国家重点实验室, 兰州, 730000
  • 收稿日期:1997-10-27 出版日期:1998-05-24 发布日期:1998-05-24
  • 通讯作者: 涂永强,男,39岁,博士,教授.
  • 作者简介:涂永强,男,39岁,博士,教授.
  • 基金资助:

    国家教育委员会博士点基金

A New Reductive Rearrangement of Allylic Epoxy Alcohols

TU Yong-Qiang, WANG Ping-Zhen, CHEN Yao-Zu   

  1. Department of Chemistry, National Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, 730000
  • Received:1997-10-27 Online:1998-05-24 Published:1998-05-24

PDF (PC)

被引次数

6

关键词: 环氧醇, 重排反应, 立体控制

Abstract: Five tertiary 2,3-epoxy alcohols with different structures and/or stereochemistry have been investigated on the reaction with aluminum isopropoxide(AIP), three of which were shown to undergo an unusual reductive rearrangement to form 1,3-diol products. Further investigation results about the substitution effects and the product's stereochemistry of this reaction were also discussed.

Key words: Epoxy alcohols, Rearrangement reaction, Stereocontrol

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