高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (11): 1721.

• 研究快报 • 上一篇    下一篇

由杂多酸衍生物制备溶致液晶

黄如丹, 费宝丽, 王恩波, 李白涛, 张素霞   

  1. 东北师范大学化学系, 长春, 130024
  • 收稿日期:1997-08-12 出版日期:1998-11-24 发布日期:1998-11-24
  • 通讯作者: 王恩波
  • 作者简介:黄如丹,女,45岁,副教授.
  • 基金资助:

    国家自然科学基金(批准号:29771006)南京大学配位化学国家重点实验室资助课题.

Synthesis of Lyotropic Liquid Crystals by Heteropoly Compounds Derivatives

HUANG Ru-Dan, FEI Bao-Li, WANG En-Bo, LI Bai-Tao, ZHANG Su-Xia   

  1. Department of Chemistry, Northeast Normal University, Changchun, 130024
  • Received:1997-08-12 Online:1998-11-24 Published:1998-11-24

关键词: 溶致液晶, 杂多酸衍生物, 吡啶配位

Abstract: Heteropoly compound, Na16 P4W30Cu4(H2O)2O112 · n H2O, has been transferred from water to benzene by phase transfer. After the surface coordinated water molecule was removed and title compound is substituted by pyridine, we get a lyotropic liquid crystal formed by heteropolycompound and small molecule formed by organic basis. It is characterized by polarimicroscope, DSCand heterothermal as well as wide angle X-ray diffraction.

Key words: Lyotropic liquid crystal, Heteropoly compounds derivatives, Coordination by pyridine

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