高等学校化学学报

高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (10): 1703.

• 研究简报 • 上一篇    

可溶性聚对苯乙炔衍生物的合成

王建营1, 李银奎2, 胡文祥1, 龙永福2   

  1. 1. 国防科工委军事医药研究发展中心, 北京, 100101;
    2. 国防科技大学材料工程与应用化学系, 长沙, 410073
  • 收稿日期:1997-11-10 出版日期:1998-10-24 发布日期:1998-10-24
  • 通讯作者: 王建营,男,30岁,助理研究员,硕士.
  • 作者简介:王建营,男,30岁,助理研究员,硕士.
  • 基金资助:

    国防科技大学预研基金资助课题.

The Synthesis of Soluble Poly (p-phenylene vinylene) Derivatives

WANG Jian-Ying1, LI Yin-Kui2, HU Wen-Xiang1, LONG Yong-Fu2   

  1. 1. The Centre of Research and Development of Medicine Pharmaceuticals, Commission of Science, Technology and Industry for National Defence, Beijing, 100101;
    2. Department of Materials Engineering and Applied Chemistry, National University of Defence Technology, Changsha, 410073
  • Received:1997-11-10 Online:1998-10-24 Published:1998-10-24

PDF (PC)

被引次数

16

关键词: 聚对苯乙炔, 烷氧取代基, 脱氯化氢反应

Abstract: Poly(2-methoxy-5-hexyloxy-p-phenylene vinylene) and poly(2-methoxy-5-nonyloxy-p-phenylene vinylene) were synthesized through dehydrochlorination with p-methoxy phenol as raw materials. The effect of solvents and substituents on polymerization and polymer solubility was discussed. The structure of polymers was identified by UV/Vis, IR and 1H NMR.

Key words: Poly(p-phenylene vinylene), Alkoxy-substituents, Dehydrochlorination

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