高等学校化学学报 ›› 1995, Vol. 16 ›› Issue (S1): 75.
YANG Wen-sheng1, LU Ran1, CHAI Xiang-dong1, CAO Yun-wei1, REN Yan-zhi1, JIANG Yue-shun1, TANG Xin-yi1, Li Tie-jin1, FU Lian-she2, SUN Gui-fen2, ZHANG Hong-jie2, J.M.Lehn3
YANG Wen-sheng1, LU Ran1, CHAI Xiang-dong1, CAO Yun-wei1, REN Yan-zhi1, JIANG Yue-shun1, TANG Xin-yi1, Li Tie-jin1, FU Lian-she2, SUN Gui-fen2, ZHANG Hong-jie2, J.M.Lehn3
摘要:
The process of molecular recognition directed self-assembling between two complementary molecular components. 5-(4-dodecyloxybenzylidene)-2,4,6-(1H, 3H)-pyrimidinetrione (B) and 4-amino-2,6-didodecylamino-l,3,5-triazine (M),was studied using fluorescence spectroscopy. It was found that it took more than 1200 h for this process to reach the equilibrium.This means that there must be other kinds of noncovalent interactions besides hydrogen bonds.This system has a positive cooperativity and B is proved to be as both the fluorescence probe and molecular components of the self-assembling.
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