高等学校化学学报

高等学校化学学报 ›› 1995, Vol. 16 ›› Issue (S1): 21.

• 研究论文 • 上一篇    下一篇

Multi-Functionalization of Vanadylorgano-phosphonate Through Intercalation

Tomokazu Iyoda1, Takashi Shimura1,2, Kenichiro Nakamura2, Kazuhito Hashimoto1,3, Akira Fujishima1,3   

  1. 1. Kanagawa Academy of Scinece and Technology, Atsugi, Kanagawa, 243-02, Japan;
    2. Dept. of Optoengineering Tokai University, Hiratsuka, Kanagawa, 259-12, Japan;
    3. Dept. of Applied Chemistry, the University of Tokyo, Tokyo 113, Japan
  • 收稿日期:1995-07-29 出版日期:1995-12-31 发布日期:1995-12-31

Multi-Functionalization of Vanadylorgano-phosphonate Through Intercalation

Tomokazu Iyoda1, Takashi Shimura1,2, Kenichiro Nakamura2, Kazuhito Hashimoto1,3, Akira Fujishima1,3   

  1. 1. Kanagawa Academy of Scinece and Technology, Atsugi, Kanagawa, 243-02, Japan;
    2. Dept. of Optoengineering Tokai University, Hiratsuka, Kanagawa, 259-12, Japan;
    3. Dept. of Applied Chemistry, the University of Tokyo, Tokyo 113, Japan
  • Received:1995-07-29 Online:1995-12-31 Published:1995-12-31

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摘要：

The intercalation of various kinds of alcohols into vanadyl-organophosphate powder is investigated mainly by elementary analysis and X-ray diffraction measurement. Not only a series of fatty alcohols but also benzylalcohol derivatives are almost quantitatively intercalated with reasonable relationships between the size of the intercalators and the increasing layer spacing. Another useful preparative method for the host thin film is developed by electrochemical treatment of a conventional V2O5 thin film.

关键词: Vanadylorganophosphonate, Intercalation, Layer spacing, Host material, Electrochemical preparation

Abstract:

The intercalation of various kinds of alcohols into vanadyl-organophosphate powder is investigated mainly by elementary analysis and X-ray diffraction measurement. Not only a series of fatty alcohols but also benzylalcohol derivatives are almost quantitatively intercalated with reasonable relationships between the size of the intercalators and the increasing layer spacing. Another useful preparative method for the host thin film is developed by electrochemical treatment of a conventional V2O5 thin film.

Key words: Vanadylorganophosphonate, Intercalation, Layer spacing, Host material, Electrochemical preparation

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