高等学校化学学报

高等学校化学学报 ›› 1995, Vol. 16 ›› Issue (S1): 196.

• 研究论文 • 上一篇    下一篇

Conductivity of One-Dimensional Phthalocyanine Compounds

GAO Yan-Min1, WANG Rong-Shun2   

  1. 1. Materials Sci. & Tech. Research Institute, Fushun Petroleum Institute, Fushun, 113001, P. R. China;
    2. Department of Chemistry, Northeast Normal University, 13002
    4. P, R. China
  • 收稿日期:1995-08-03 出版日期:1995-12-31 发布日期:1995-12-31
  • 基金资助:

    National Natural Science Foundation of China

Conductivity of One-Dimensional Phthalocyanine Compounds

GAO Yan-Min1, WANG Rong-Shun2   

  1. 1. Materials Sci. & Tech. Research Institute, Fushun Petroleum Institute, Fushun, 113001, P. R. China;
    2. Department of Chemistry, Northeast Normal University, 13002
    4. P, R. China
  • Received:1995-08-03 Online:1995-12-31 Published:1995-12-31
  • Supported by:

    National Natural Science Foundation of China

PDF (PC)

摘要：

Phthalocyanine, compounds(MPcL) containing the bridge radical ligand were studied by using the method of EHMOACC. Calculation results indicate that the charge carriers are mainly from thermal excitation of semiconductor, where charges are transferred by both hole and electron; the information manifested in the electron energy band and electric conductivity deduced by means of migration formula of the charge carrier at room temperature are in accordance with the experiment facts in the main.

关键词: Conductivity, Phthalocyanine, Quantum chemistry

Abstract:

Phthalocyanine, compounds(MPcL) containing the bridge radical ligand were studied by using the method of EHMOACC. Calculation results indicate that the charge carriers are mainly from thermal excitation of semiconductor, where charges are transferred by both hole and electron; the information manifested in the electron energy band and electric conductivity deduced by means of migration formula of the charge carrier at room temperature are in accordance with the experiment facts in the main.

Key words: Conductivity, Phthalocyanine, Quantum chemistry

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