高等学校化学学报

高等学校化学学报 ›› 1995, Vol. 16 ›› Issue (S1): 13.

• 研究论文 • 上一篇    下一篇

Preparation of Nanoparticulate [PMo11Cu(H2O)O39]5--n-C18H37NH2 Film Using Langmuir-BIodgett Method

PENG Xiao-gang1, ZHANG Xin-tong1, LI Lin-song1, QIN Zhu-jie1, XIAO Liang-zhi1, LI Tie-jin1, Shen Chao2   

  1. 1. Department of Chemistry, Jilin University, Changchun, 130023, P. R. China;
    2. Department of of Fundamental Science, Jiamusi Institute of Technology Jiamusi, 154007, P, R. China
  • 收稿日期:1995-08-03 出版日期:1995-12-31 发布日期:1995-12-31
  • 基金资助:

    National Natural Science Foundation of China

Preparation of Nanoparticulate [PMo11Cu(H2O)O39]5--n-C18H37NH2 Film Using Langmuir-BIodgett Method

PENG Xiao-gang1, ZHANG Xin-tong1, LI Lin-song1, QIN Zhu-jie1, XIAO Liang-zhi1, LI Tie-jin1, Shen Chao2   

  1. 1. Department of Chemistry, Jilin University, Changchun, 130023, P. R. China;
    2. Department of of Fundamental Science, Jiamusi Institute of Technology Jiamusi, 154007, P, R. China
  • Received:1995-08-03 Online:1995-12-31 Published:1995-12-31
  • Supported by:

    National Natural Science Foundation of China

PDF (PC)

摘要：

Nanoparticulate [PMo11Cu(H2O)O39]5--(PCuMo11)-n-C18H37NH2 composite monolayer can be formed at the air-liquid interface using nanoparticulate PCuMo11 as the subphase. The area extrapolated to π=0 is 0.27 nm2 per hydrocarbon chain of the monolayer. The collapse pressure is about 3.5×10-1 N. The composite monolayer was deposited on the solid substrate using the LB technique. The XPS characterization of the composite monolayer showed that in the film the directional alignment of PCuMo11, molecules was in the direction of Cu atoms close to the amino groups of the octadecylamine moleculos.

关键词: PCuMo11-n-C18H37NH2 composite monolayer, XPS, LB technique, Nanoparticle

Abstract:

Nanoparticulate [PMo11Cu(H2O)O39]5--(PCuMo11)-n-C18H37NH2 composite monolayer can be formed at the air-liquid interface using nanoparticulate PCuMo11 as the subphase. The area extrapolated to π=0 is 0.27 nm2 per hydrocarbon chain of the monolayer. The collapse pressure is about 3.5×10-1 N. The composite monolayer was deposited on the solid substrate using the LB technique. The XPS characterization of the composite monolayer showed that in the film the directional alignment of PCuMo11, molecules was in the direction of Cu atoms close to the amino groups of the octadecylamine moleculos.

Key words: PCuMo11-n-C18H37NH2 composite monolayer, XPS, LB technique, Nanoparticle

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