高等学校化学学报

高等学校化学学报 ›› 1995, Vol. 16 ›› Issue (S1): 125.

• 研究论文 • 上一篇    下一篇

In-Situ Spectroelectrochemical Measurement of Azobenzene Containing Self-Assembled Monolayers

R.Wang1,2, T.Iyoda2, D.A.Tryk1, K.Hashimoto1,2, Akira Fujishima1,2, I.Bae3, D.A.Scherson3   

  1. 1. Department of Applied Chemistry, Faculty of Engineering, The University of Tokyo, Hongo, Bunkyoku, Tokyo, 113, Japan;
    2. Photochemical Conversion Materials Project, Kanagawa Academy of Science and Technology Laboratory, 1583, liyama, Atsugi, Kanagawa 243-02, Japan;
    3. Case Center for Electrochemical Sciences and the Department of Chemistry, Case Western Reserve Uiversity, Ohio 44106, U. S. A
  • 收稿日期:1995-08-24 出版日期:1995-12-31 发布日期:1995-12-31

In-Situ Spectroelectrochemical Measurement of Azobenzene Containing Self-Assembled Monolayers

R.Wang1,2, T.Iyoda2, D.A.Tryk1, K.Hashimoto1,2, Akira Fujishima1,2, I.Bae3, D.A.Scherson3   

  1. 1. Department of Applied Chemistry, Faculty of Engineering, The University of Tokyo, Hongo, Bunkyoku, Tokyo, 113, Japan;
    2. Photochemical Conversion Materials Project, Kanagawa Academy of Science and Technology Laboratory, 1583, liyama, Atsugi, Kanagawa 243-02, Japan;
    3. Case Center for Electrochemical Sciences and the Department of Chemistry, Case Western Reserve Uiversity, Ohio 44106, U. S. A
  • Received:1995-08-24 Online:1995-12-31 Published:1995-12-31

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被引次数

2

摘要：

The electrochemical behavior of an azobenzene containing self-assembled monolayer (SAM) has been examined by means of in-situ Fourier transform infrared reflection absorption (FTIRRA) spectroscopy. The electrochemical reduction product of azobenzene has been confirmed to be hydrazobenzene. A stable and reversible process in both electrochemistry and architecture has been found in the monolayer film.

关键词: Azobenzene, Self-assembled monolayer, FTIR, In-situ measurement

Abstract:

The electrochemical behavior of an azobenzene containing self-assembled monolayer (SAM) has been examined by means of in-situ Fourier transform infrared reflection absorption (FTIRRA) spectroscopy. The electrochemical reduction product of azobenzene has been confirmed to be hydrazobenzene. A stable and reversible process in both electrochemistry and architecture has been found in the monolayer film.

Key words: Azobenzene, Self-assembled monolayer, FTIR, In-situ measurement

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