高等学校化学学报

高等学校化学学报 ›› 1995, Vol. 16 ›› Issue (9): 1471.

• 论文 • 上一篇    下一篇

氨基树脂交联型聚合物的合成及其取向松弛

杨春才, 王化滨, 胡慧贞, 景遐斌, 韩孝族, 王佛松   

  1. 中国科学院长春应用化学研究所高分子物理联合开放实验室, 长春, 130022
  • 收稿日期:1994-10-24 修回日期:1995-03-12 出版日期:1995-09-24 发布日期:1995-09-24
  • 通讯作者: 王化滨
  • 作者简介:杨春才,男,30岁,博士后.
  • 基金资助:

    国家自然科学基金

Synthesis and Orientation of Melaminealdehyde Resin Crosslinked Polymers

YANG Chun-Cai, WANG Hua-Bin, HU Hui-Zhen, JING Xia-Bin, HAN Xiao-Zu, WANG Fo-Song   

  1. Polymer Phys . Lab., Changchun Institute of Applied Chemistry, Academia Sinica, Changchun, 130022
  • Received:1994-10-24 Revised:1995-03-12 Online:1995-09-24 Published:1995-09-24

PDF (PC)

摘要： 用双羟基偶氮(或氧化偶氮)苯化合物与对苯二甲酰氯缩聚反应合成了端羟基偶氮(或氧化偶氮)苯低聚物。将其与丁醇醚化氨基树脂进行电场极化交联反应合成交联型非线性光学聚合物。利用红外光谱和紫外可见吸收光谱分别对交联反应、电场极化取向稳定性进行了研究。

关键词: 端羟基低聚物, 丁醇醚化氨基树脂, 交联聚合物, 电晕极化, 取向松弛

Abstract: Three kinds of hydroxy-terminated oligomers were synthesized and characterized by IR, DSC and GPC. The oligomers were crosslinked by melaminealdehyde resin. The orientation and relaxation of the poled and crosslinked polymers were studied by UV-Vis spectra. It was shown that polymers had high orientational stability after corona-poling and crosslinking.

Key words: Hydroxy-terminated oligomer, Melaminealdehyde resin, Crosslinked polymer, Corona-poling, Orientation and relaxation

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