高等学校化学学报 ›› 1995, Vol. 16 ›› Issue (7): 1104.
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郭荣, 朱文庆, 陈宗淇, 祁琳, 沈明
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国家自然科学基金
GUO Rong, ZHU Wen-Qing, CHEN Zong-Qi, QI Lin, SHEN Ming
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摘要: 研究了醇对非离子型表面活性剂浊点的影响,发现直链醇的碳原子数小于4时随着其在表面活性剂中含量的增加浊点上升;当碳原子数大于4时,则随着醇含量的增加浊点下降。醇的构型对浊点起着重要作用。
关键词: 浊点, 非离子型表面活性剂, 直链醇, 支链醇
Abstract: The solution of straight chain alcohols made the cloud points of Triton X-100 system increase if the number of alcohol carbon nc<4, and decrease if nc≥4. The longer the chain of straight chain alcohol, the stronger the effect on the cloud point. When the branch chain alcohols were added in the Triton X-100 system, the less the space resistance and the solubility of branch chain alcohols, the lower the cloud points of Tirton X-100 system. The effect of alcohols on the cloud points of Triton X-100 was related to the hydrophilicity and space structure of alcohol and solubilization position in the micelle.
Key words: Cloud point, Nonionic surfactant, Straight chain alcohol, Branch chain alcohol
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郭荣, 朱文庆, 陈宗淇, 祁琳, 沈明. 醇对非离子型表面活性剂浊点的影响. 高等学校化学学报, 1995, 16(7): 1104.
GUO Rong, ZHU Wen-Qing, CHEN Zong-Qi, QI Lin, SHEN Ming . The Effects of Alcohols on the Cloud Points of Nonionic Surfactant. Chem. J. Chinese Universities, 1995, 16(7): 1104.
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http://www.cjcu.jlu.edu.cn/CN/Y1995/V16/I7/1104