高等学校化学学报 ›› 1995, Vol. 16 ›› Issue (7): 1104.

• 论文 • 上一篇    下一篇

醇对非离子型表面活性剂浊点的影响

郭荣, 朱文庆, 陈宗淇, 祁琳, 沈明   

  1. 青岛化工学院应用化学系, 青岛, 266042
  • 收稿日期:1994-08-06 修回日期:1994-10-19 出版日期:1995-07-24 发布日期:1995-07-24
  • 通讯作者: 陈宗淇
  • 作者简介:郭荣,男,40岁,教授.
  • 基金资助:

    国家自然科学基金

The Effects of Alcohols on the Cloud Points of Nonionic Surfactant

GUO Rong, ZHU Wen-Qing, CHEN Zong-Qi, QI Lin, SHEN Ming   

  1. Department of Applied Chemistry, Qingdao Institute of Chemical Technology, Qingdao, 266042
  • Received:1994-08-06 Revised:1994-10-19 Online:1995-07-24 Published:1995-07-24

摘要: 研究了醇对非离子型表面活性剂浊点的影响,发现直链醇的碳原子数小于4时随着其在表面活性剂中含量的增加浊点上升;当碳原子数大于4时,则随着醇含量的增加浊点下降。醇的构型对浊点起着重要作用。

关键词: 浊点, 非离子型表面活性剂, 直链醇, 支链醇

Abstract: The solution of straight chain alcohols made the cloud points of Triton X-100 system increase if the number of alcohol carbon nc<4, and decrease if nc≥4. The longer the chain of straight chain alcohol, the stronger the effect on the cloud point. When the branch chain alcohols were added in the Triton X-100 system, the less the space resistance and the solubility of branch chain alcohols, the lower the cloud points of Tirton X-100 system. The effect of alcohols on the cloud points of Triton X-100 was related to the hydrophilicity and space structure of alcohol and solubilization position in the micelle.

Key words: Cloud point, Nonionic surfactant, Straight chain alcohol, Branch chain alcohol

TrendMD: