高等学校化学学报

高等学校化学学报 ›› 1995, Vol. 16 ›› Issue (7): 1040.

• 论文 • 上一篇    下一篇

5,6-二亚甲基双环[2.2.1]庚-2-醇及其衍生物的旋光与构型

邹志琛, 李希友, 官景渠   

  1. 山东师范大学化学系, 济南, 250014
  • 收稿日期:1994-09-26 修回日期:1995-01-29 出版日期:1995-07-24 发布日期:1995-07-24
  • 通讯作者: 邹志璨,男,47岁,教授.
  • 作者简介:邹志璨,男,47岁,教授.

Optical Rotation and Configuration of 5,6-Dimethylidenebicyclo-[2. 2. 1]heptan-2-ol and Its Derivatives

ZHOU Zhi-Chen, LI Xi-You, GUAN Jing-Qu   

  1. Department of Chemistry, Shandong Teachers' University, Jinan, 250014
  • Received:1994-09-26 Revised:1995-01-29 Online:1995-07-24 Published:1995-07-24

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摘要： 从(-)-(1S,2R,4S)-5,6-二亚甲基双环[2.2.1]庚-2-醇(1)和(-)-(1S,2S,4S)-5,6-二亚甲基双环[2.2.1)庚-2-醇(Ⅱ)出发,合成了它们的醚类和取代苯甲酸酯类光学纯的衍生物。通过[α]D。测定和构型分析,发现它们是含有3个手性碳(C1,C2和C4)的桥环化合物,其旋光性与构型的关系均符合可极化度多级圆球不对称性模型。

关键词: 手性桥环化合物, 旋光与构型, 可极化度多级圆球不对称性模型

Abstract: Some optical pure derivatives, ethers and esters, of 5, 6-dimethylidenebicyclo [2. 2.1]heptan-2-ol were prepared. The relationship between their optical rotation and configuration fits the asymmetric polarizability of multistage sphere model.

Key words: Chiral bridged ring compounds, Optical rotation and configuration, Model of asymmetric polarizability of multistage sphere

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