高等学校化学学报

高等学校化学学报 ›› 1995, Vol. 16 ›› Issue (7): 1024.

• 论文 • 上一篇    下一篇

耦联酶催化反应电化学体系的表面循环伏安行为的数字模拟

孔继烈, 邓家祺   

  1. 复旦大学化学系, 上海, 200433
  • 收稿日期:1994-07-18 修回日期:1995-03-10 出版日期:1995-07-24 发布日期:1995-07-24
  • 通讯作者: 邓家棋
  • 作者简介:孔继烈,男,31岁,博士,副教授.
  • 基金资助:

    国家自然科学基金

Digital Simulation of Cyclic Voltammetry for Response of Enzyme-Mediator Modified Electrode

KONG Ji-Lie, DENG Jia-Qi   

  1. Dept. of Chem., Fudan Univ., Shanghai, 200433
  • Received:1994-07-18 Revised:1995-03-10 Online:1995-07-24 Published:1995-07-24

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摘要： 采用数字模拟法对耦联酶催化反应体系的表面循环伏安行为进行了研究,讨论了介体氧化还原动力学、酶催化动力学及介体催化酶动力学等参数对循环伏安图的影响,并用实验进行了验证。

关键词: 介体酶修饰电极, 数字模拟, 循环伏安行为

Abstract: Digital simulation was employed to study the cyclic voltammetry(CV) response of enzyme-mediator modified electrode. The digital model was built and the effect of kinetic parameters on CV curves was discussed. The digital simulation could help to devise or improve the properties of such kind of enzyme-mediator modified electrode.

Key words: Enzyme-mediator modified electrode, Digital simulation, Cyclic voltammetry

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