高等学校化学学报 ›› 1995, Vol. 16 ›› Issue (12): 1868.

• 研究简报 • 上一篇    下一篇

连串反应速差动力学分析中的数据处理方法的研究

吴新国, 蔡汝秀, 林智信, 程介克   

  1. 武汉大学化学系, 武汉, 430072
  • 收稿日期:1994-12-14 修回日期:1995-03-30 出版日期:1995-12-24 发布日期:1995-12-24
  • 通讯作者: 蔡汝秀
  • 作者简介:吴新国,男,30岁,博士研究生
  • 基金资助:

    国家自然科学基金

The Investigation of Data Processing Method for Differential Rate Kinetic Analysis Based on Successive Reactions

WU Xin-Guo, CAI Ru-Xiu, LIN Zhi-Xin, CHENG Jie-Ke   

  1. Department of Chemistry, Wuhan University, Wuhan, 430072
  • Received:1994-12-14 Revised:1995-03-30 Online:1995-12-24 Published:1995-12-24

关键词: 连串反应, 速差动力学分析, 比例方程法, 肾上腺素, 去甲肾上腺素

Abstract: A data processing method for differential rate kinetic analysis based on successive reactions is described.The method is a new kind of proportional equation established by using parameters of two reaction rates which are measured at different period of reaction times.The difference bet en two successive reactions can be exploited more extensively by using this method,and analysis accuracy can be increased.The simultaneous determination of epinephrine and norepinephrin in a mixture is performed by this method,errors found are obviously smaller than those obtained by traditional proportional equation and extension proportional equatin.

Key words: Successive reactions.Differential rate kinetic analysis, Proportional equation, Epinephrine, Norepinephring

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