高等学校化学学报

高等学校化学学报 ›› 1994, Vol. 15 ›› Issue (5): 741.

• 论文 • 上一篇    下一篇

含羧甲磺酰基水暂溶性分散染料的研究──中间体及染料的脱羧反应动力学

王梅1, 潘鑫2, 刘金香3, 高秀英3   

  1. 1. 大连合成纤维研究所;
    2. 大连理工大学精细化工系, 大连, 116012;
    3. 中国科学院大连化学物理研究所
  • 收稿日期:1993-06-01 修回日期:1993-09-10 出版日期:1994-05-24 发布日期:1994-05-24
  • 通讯作者: 潘鑫
  • 作者简介:王梅,女,32岁,工程师.
  • 基金资助:

    国家自然科学基金

A Study on Temporarily Water-soluble Disperse Dyes Containing Carboxymethylsulfonyl Group ──The Kinetics of Decarboxylation of Intermediates and Dyes

WANG Mei1, Pan Xin2, LIU Jin-Xiang3, GAO Xiu-Ying3   

  1. 1. Dalian Institute of Synthesis Fibre, Dalian;
    2. Department of Fine Chemical Engineering, Dalin Uniuersity of Technology, Dalian, 116012;
    3. Dallian Institute of Chemical Physics, Academia Sinica, Dalian
  • Received:1993-06-01 Revised:1993-09-10 Online:1994-05-24 Published:1994-05-24

PDF (PC)

被引次数

6

摘要： 用热天平研究了中间体及染料的非等温脱羧反应动力学,用Avrami-Erofeev成核和生长模型关联出反应动力学方程,并算出动力学参数。

关键词: 分散染料, 水暂溶性, 羧甲磺酰基, 脱羧动力学

Abstract: The kinetics of decarboxylation of intermediates and dyes containing carboxymethylsulfonyl group was studied by thermogravlmetry. The temperatures of decarboxylation of initial,final,Tmax and intensive decomposition were obtained through experiment. The Avrami-Erofeev equation of n=1,which is the same formation as the first order chemical reaction, was used to describe the decarboxylation process. The apparent kinetic parameters were obtained.There is compensating effect between activation energy and frequency factor for these different intermediates and dyes.

Key words: Disperse dye, Temporarily watersolubility, Carboxymethylsulfonyl group, Decarboxylation kinetics

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