高等学校化学学报

高等学校化学学报 ›› 1994, Vol. 15 ›› Issue (3): 360.

• 论文 • 上一篇    下一篇

卷积伏安法的半微分新算法

谢天尧, 莫金垣   

  1. 中山大学化学系, 广州, 510275
  • 收稿日期:1993-03-15 修回日期:1993-09-20 出版日期:1994-03-24 发布日期:1994-03-24
  • 通讯作者: 莫金垣
  • 作者简介:谢天尧,男,27岁,博士生.
  • 基金资助:

    国家自然科学基金

The New Numerical Method of Semiderivation for Convolution Voltammetry

XIE Tian-Yao, MO Jin-Yuan   

  1. Department of Chemistry, Zhongshan University, Guangzhou, 510275
  • Received:1993-03-15 Revised:1993-09-20 Online:1994-03-24 Published:1994-03-24

PDF (PC)

被引次数

5

摘要： 从半微分算符的基本性质出发,用黎曼-斯提杰斯积分展开式得到两个关于半微分运算的新表达式。应用所得的算式在无因次量纲上讨论了线性扫描伏安法的电流函数,得到了与G1方程完全一致的结果,但表达式更直观。

关键词: 半微分, 数值方法, 卷积伏安法

Abstract: Two new arithmetic formulas Of semiderivation for convolution voltammetry were presented based on the semiderivative property.With the derived formulas, the current function of linear sweep voltammetry was discussed in non-dimensional level,and the results are in complete accord with the G1 equation's under the same given parameters.In addition,the proposed arithmetic would afford direct and clear theoretical evidence for studying the link between linear sweep voltammetry and staircase voltammetry.

Key words: Semiderivation, Numerical method, Convolution Voltammetry

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