高等学校化学学报 ›› 1994, Vol. 15 ›› Issue (10): 1538.

• 论文 • 上一篇    下一篇

球型胶粒间的相互作用能─Derjaguin法的改进

王好平, 金军, L. Blum   

  1. 1. 抚顺石油学院石油化工系, 抚顺, 113001;
    2. 波多黎各大学物理系, 美国
  • 收稿日期:1993-12-14 修回日期:1994-03-19 出版日期:1994-10-24 发布日期:1994-10-24
  • 通讯作者: 王好平,男,52岁,教授.
  • 作者简介:王好平,男,52岁,教授.

Interaction Energy Between Spherical Colloidal Particles─The Improvement On Derjaguin Method

WANG Hao-Ping, Jin Jun, L. Blum   

  1. 1. Department of Petrochemical Engineering, Fushun Petroleum, Fushun, 113001;
    2. Department of Physics, University of Puerto Rico, San Juan, U.S.A.
  • Received:1993-12-14 Revised:1994-03-19 Online:1994-10-24 Published:1994-10-24

摘要: 对求算球型胶体颗粒相互作用能的Derjaguin法进行了适当的修正,并由此得出简单的解析表达式。对低电位条件下等同和不等同球颗粒的计算结果表明,该法拓宽了Derjaguin公式的应用范围,提高了计算结果的精确度。

关键词: 球颗粒, DLVO理论, 排斥能, 双电层

Abstract: The correction to classical Derjaguin method has been made in the formulae for the double layer interaction at constant surface potential between two identical and between two dissimilar spheres.The expressions which can be applied to any ka and kHare obtained, in which k is Parameter, a is the radius of particles, His the shortest distance between the two spheres.The improved Derjaguin approximation opens up a usual area of familiar Derjagain formulae, and gives the exact results.

Key words: Spheres, DLVO theory, Repulsive energy, Electrical double layer

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