高等学校化学学报

高等学校化学学报 ›› 1993, Vol. 14 ›› Issue (8): 1131.

• 研究论文 • 上一篇    下一篇

气相中C60与多氯代乙烷的反应

刘子阳, 郭兴华, 宋凤瑞, 刘淑莹   

  1. 中国科学院长春应用化学研究所, 长春 130022
  • 收稿日期:1992-09-27 修回日期:1992-12-02 出版日期:1993-08-24 发布日期:1993-08-24
  • 通讯作者: 刘淑莹
  • 作者简介:第一作者:男, 30岁, 博士后.
  • 基金资助:

    长春应用化学研究所结构化学开放实验室资助

Reactions of C60 with Multichloroethanes in Gas Phase

LIU Zi-Yang, GUO Xing-Hua, SONG Feng-Rui, LIU Shu-Ying   

  1. Changchun Institute of Applied Chemistry, Academia Sinica, Changchun, 130022
  • Received:1992-09-27 Revised:1992-12-02 Online:1993-08-24 Published:1993-08-24

摘要： 在质谱仪离子源化学电离条件下.C60分别与1,2-二氯乙烷、1,1,2-三氯乙烷、1,1,1-三氯乙烷及1,1,2,2-四氯乙烷的主要碎片离子反应,生成多种C60的加合离子.显示了气相中C60的化学活泼性.

关键词: C60, 气相离子分子反应, 多氯代乙烷

Abstract: In the ion source of mass spectrometer, the reactions between C60 with the main fragments of 1,2-dichloroethane, 1,1,2-trichloroethane, 1,1,1-trichloroethane and 1,1,2,2-tetra-chloroethane were performed and the corresponding adduct ions were formed by using a chemical inization mathod.C60 is very active to many organic ions in the gas phase.The odd electron fragments were more reactive with C60 than the even electron ions, this shows the radical capture property of C60.

Key words: Buckminsterf ullerene, Gas-phase ion-molecular reaction, Multichloroethane

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