高等学校化学学报 ›› 1993, Vol. 14 ›› Issue (7): 944.

• 研究论文 • 上一篇    下一篇

含羟基芳基或氨基芳基的磷酰胺酯衍生物的合成

陈茹玉, 安逢龙, 白明章, 孙丽娟   

  1. 南开大学元素有机化学研究所, 天津 300071
  • 收稿日期:1992-10-30 修回日期:1993-03-18 出版日期:1993-07-24 发布日期:1993-07-24
  • 通讯作者: 陈茹玉
  • 作者简介:第一作者:女, 73岁, 博士, 教授(学部委员).
  • 基金资助:

    国家自然科学基金

Synthesis of Derivatives of Amidophosphoric Esters Containing Hydroxyphenyl or Aminophenyl Group

CHEN Ru-Yu, AN Feng-Long, BAI Ming-Zhang, SUN Li-Juan   

  1. Institute of Elemento-Organic Chemistry, Tianjin, 300071
  • Received:1992-10-30 Revised:1993-03-18 Online:1993-07-24 Published:1993-07-24

摘要: 采用均相反应的方法合成了6个含羟基芳基或氨基芳基的磷酰胺酯衍生物:[(ClCH2CH2)2NP(O)(OPh)(XArY)](X:O,NH;Y:m或p-OH或NH2).用元素分析、红外光谱、氢核磁共振谱及质谱证实了它们的组成及结构.

关键词: 磷酰胺酯, 磷酰胺酯衍生物, 均相反应

Abstract: Six derivatives of amidophosphoric esters containing hydroxyphenyi or aminophenyl group were synthesized by a homogeneous reaction.The products.[(ClCH2CH2)2NP(O) (OPh) (XArY)] (X:O,NH; Y:m or p-OH, NH) were confirmed by elemental analysis and IR, 1H NMR, MSspec-trometry.

Key words: Amidophosphoric ester, Derivatives of amidophosphoric ester, Homogeneous reaction

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