高等学校化学学报

高等学校化学学报 ›› 1993, Vol. 14 ›› Issue (7): 1033.

• 研究简报 • 上一篇    

基团转移聚合合成PMMA-PEA-PAN嵌段共聚物的研究

夏海平, 陈萍, 郭舰, 丁马太   

  1. 厦门大学化学系, 厦门 361005
  • 收稿日期:1992-01-14 修回日期:1992-03-30 出版日期:1993-07-24 发布日期:1993-07-24
  • 通讯作者: 夏海平
  • 作者简介:第一作者:男, 29岁, 硕士, 副教授.
  • 基金资助:

    国家自然科学基金

Synthesis of PMMA-PEA-PAN Block Polymer by Group Transfer Polymerization

XIA Hai-Ping, CHEN Ping, GUO Jian, DING Ma-Tai   

  1. Department of Chemistry, Xiamen University, Xiamen, 361005
  • Received:1992-01-14 Revised:1992-03-30 Online:1993-07-24 Published:1993-07-24

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关键词: 三元嵌段共聚物, 基团转移聚合, 聚丙烯腈, 聚(甲基)丙烯酸酯

Abstract: Aseries of PMMA-PEA-PANblock copolymers were synthesized by means of group transfer polymerization (GTP) and using dimethyl ketene methyl trimethylsilyl acetal as initiator and n-Bu4NH (PhCO2)2 as catalyst.The terpolymers were characterized by GPCand 1H NMR.

Key words: Block copolymer, Group transfer polymerization, Polyacrylonitrile, Poly(meth)acrylate

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