微环电极上阶梯扫描伏安法可逆波理论及验证

高等学校化学学报 ›› 1993, Vol. 14 ›› Issue (4): 489.

微环电极上阶梯扫描伏安法可逆波理论及验证

吴志斌, 张祖训

南京大学化学系, 南京 210008

收稿日期:1992-06-14 修回日期:1992-11-01 出版日期:1993-04-24 发布日期:1993-04-24
通讯作者: 张祖训
基金资助:
高等学校博士学科点专项科学基金

The Theory of Reversible Wave with Staircase Sweep Voltammetry at Microring Electrodes and Its Experimental Verification

WU Zhi-Bin, ZHANG Zu-Xun

Department of Chemistry, Nanjing University, Nanjing, 210008

Received:1992-06-14 Revised:1992-11-01 Online:1993-04-24 Published:1993-04-24

摘要/Abstract

关键词: 阶梯扫描伏安法, 微环电极, 可逆波理论

Abstract: In this paper, the theory of reversible wave with staircase sweep voltammetry at microring electrodes is derived.The properties of current-potential curves have been discussed in detail.In order to examine the validity of the theory, experimental studies with K₄Fe(CN)₆ in 0.5 mol/L KCl solution were carried out at platinum and gold microring electrodes.The experimental results are in good agreement with the theoretical ones.

Key words: Staircase sweep voltammetry, Microring electrode, The theory of reversible wave

TrendMD:

吴志斌, 张祖训. 微环电极上阶梯扫描伏安法可逆波理论及验证. 高等学校化学学报, 1993, 14(4): 489.

WU Zhi-Bin, ZHANG Zu-Xun . The Theory of Reversible Wave with Staircase Sweep Voltammetry at Microring Electrodes and Its Experimental Verification. Chem. J. Chinese Universities, 1993, 14(4): 489.

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