高等学校化学学报

高等学校化学学报 ›› 1993, Vol. 14 ›› Issue (4): 480.

• 研究简报 • 上一篇    下一篇

吸附模式识别方法及其应用

王长发   

  1. 武汉大学化学系, 武汉 430072
  • 收稿日期:1992-04-01 修回日期:1992-09-01 出版日期:1993-04-24 发布日期:1993-04-24
  • 基金资助:

    国家自然科学基金

Adsorption Pattern Recognition and Its Application in Adsorptive Polarographic Wave

WANG Chang-Fa   

  1. Department of Chemistry, Wuhan University, Wuhan, 430072
  • Received:1992-04-01 Revised:1992-09-01 Online:1993-04-24 Published:1993-04-24

PDF (PC)

被引次数

2

关键词: 吸附模式识别, 四(4-三甲胺苯基)卟啉, 偶氮硝羟, 线性拟合

Abstract: In this paper, a adsorption equation, βC=[0/(1-0) ]"exp(g'0), is proposed as a general adsorption pattern recongnition, on which we are able to recognize isotherm of the electroactive species adsorbed on electrode, and to estimate adsorption parameters.It was applied to the inverstigation of the adsorptions of T(4-TMAP)Pand CNAon DME, The results show that the former obeys Langmuir isotherm, the adsorption equation is [θ/(l-θ) ]0.96=7.76×106×e-0.240×C, and the latter obeys Frumkin isotherm, the adsorption equation [θ/(l--θ)]1.03=1.18×105×102.220×C, These are consistent with those of literatures.

Key words: Adsorption pattern recognition, T(4-TMAP)P, CNA, Linear fitting

TrendMD: