高等学校化学学报 ›› 1993, Vol. 14 ›› Issue (11): 1531.

• 研究简报 • 上一篇    下一篇

镓-荧光镓极谱络合吸附波的研究

李南强, 贺维军   

  1. 北京大学化学系, 北京 100871
  • 收稿日期:1992-11-30 修回日期:1993-02-16 出版日期:1993-11-24 发布日期:1993-11-24
  • 通讯作者: 李南强, 男, 61岁, 教授.
  • 作者简介:李南强, 男, 61岁, 教授.
  • 基金资助:

    国家自然科学基金

Studies on Polarographic Adsorptive Complex Wave of Gallium (Ⅲ)-Lumogallion

LI Nan-Qiang, HE Wei-Jun   

  1. Department of Chemistry, Peking University, Beijing, 100871
  • Received:1992-11-30 Revised:1993-02-16 Online:1993-11-24 Published:1993-11-24

关键词: 镓, 荧光镓, 单扫极谱法

Abstract: In ClCH2COOH-ClCH2COONa buffer solution at pH 2.8, a sensitive adsorptive complex wave of Ga(Ⅲ)-lumogallion(LMG) was obtained by single-sweep polarography.The detection limit is down to 8.0× 10-9 mol/L.The proposed method has been applied to the determination of gallium content in catalyst.The composition of the complex was detected as Ga(Ⅲ):LMG=1:1.The rate constant of the surface electrochemical reaction was determined as k8=0.56 s-1.

Key words: Gallium.Lumogallion, Single-sweep polarography

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