高等学校化学学报

高等学校化学学报 ›› 1993, Vol. 14 ›› Issue (10): 1349.

• 研究论文 • 上一篇    下一篇

P-Cu-Mo杂多阴离子柱撑水滑石的制备

贺鹤鸣, 孙铁, 蒋大振   

  1. 吉林大学化学系, 长春 130023
  • 收稿日期:1993-04-15 修回日期:1993-08-07 出版日期:1993-10-24 发布日期:1993-10-24
  • 通讯作者: 孙铁
  • 作者简介:贺鹤鸣, 男, 27岁, 硕士
  • 基金资助:

    国家自然科学基金

Preparation of Pillared Hydrotalcite with PCuMo11 Heteropolyanion

HE He-Ming, SUN Tie, JIANG Da-Zhen   

  1. Department of Chemistry, Jilin University, Changchun, 130023
  • Received:1993-04-15 Revised:1993-08-07 Online:1993-10-24 Published:1993-10-24

PDF (PC)

被引次数

37

关键词: 杂多化合物, 插入, 柱撑水滑石

Abstract: The transition-metal ion was introduced into the Keggin structure in terms of the degradation of heteropoly acid.The compound was intercalated into the layered region of the hy-drotalcitelike[Zn,Al(NO3-)] in the microwave field.It is the first time to prepare the hydrotal-cite pillared with PCuMo115- heteropolyanion.The product possesses a regular layered structure and a good crystallinity.The NO3- ion existing in the layered region was substituted completely by heteropolyanion.The heteropoly compound intercalated in the layered region of hydrotalcite still has a strong ESRsignal.The experiment results show that Cu with C4v symmetry distributes uniformly in the Keggin structure and exists in a cubic cone field with pentadentate.

Key words: Heteropolycompound, Intercalation, Pillared hydrotalcite

TrendMD: