含长链烷基的单羧基卟啉的合成及LB膜特性

高等学校化学学报 ›› 1992, Vol. 13 ›› Issue (8): 1092.

含长链烷基的单羧基卟啉的合成及LB膜特性

罗毅, 吴萱阶, 陈彰评, 姜中兴

武汉大学化学系, 430072

收稿日期:1991-09-30 出版日期:1992-08-24 发布日期:1992-08-24
通讯作者: 吴萱阶
基金资助:
国家自然科学基金

The Synthesis of A Novel Amphiphilic Porphyrin and the Properties of LB Films

LUO Yi, WU Xuan-Jie, CHEN Zhang-Ping, JIANG Zhong-Xing

Department of Chemistry, Wuhan University, 430072

Received:1991-09-30 Online:1992-08-24 Published:1992-08-24

摘要/Abstract

摘要： 近年来,国际上对有机光电子材料的研制和开发已成为热门课题。具有优良光电特性的卟啉分子的合成及其LB膜的结构和特性的研究,已引起人们的重视^[1,2]。本工作设计和合成了一种新型的含长链烷基的单羧基双亲性卟啉(Ⅳ),其结构见下图,它能在水面上展开成稳定的单层膜,并且进一步研究了这种超薄膜的结构和性质。

关键词: 双亲性卟啉, 单层LB膜, 多层LB膜

Abstract: The synthesis of a novel amphiphilic porphyrin(IV) containing a long aliphatic chain is detailed.The mono-and multilayers of porphyrin(IV) were prepared and the structure was studied by STM(Scanning Tunnelling Microscope).UV-Vis spectra and fluorescence spectra were recorded in the solution and in LBfilms.

Key words: Amphiphilic porphyrin, Monolayer LB films, Multilayer LB films

TrendMD:

罗毅, 吴萱阶, 陈彰评, 姜中兴. 含长链烷基的单羧基卟啉的合成及LB膜特性. 高等学校化学学报, 1992, 13(8): 1092.

LUO Yi, WU Xuan-Jie, CHEN Zhang-Ping, JIANG Zhong-Xing. The Synthesis of A Novel Amphiphilic Porphyrin and the Properties of LB Films. Chem. J. Chinese Universities, 1992, 13(8): 1092.