量子电化学的交换电流表达式

高等学校化学学报 ›› 1992, Vol. 13 ›› Issue (6): 798.

量子电化学的交换电流表达式

张遴绍

吉林大学化学系, 长春, 130023

收稿日期:1991-05-14 出版日期:1992-06-24 发布日期:1992-06-24

An Expression of Quantum Electrochemistry for Exchange Current

ZHANG Lin-shao

Department of Chemistry, Jllin University, Changchun, 130023

Received:1991-05-14 Online:1992-06-24 Published:1992-06-24

摘要/Abstract

摘要： 本文根据热活化理论的电流密度一般式得到了交换电流表达式,计算了Fe和Ni电化学沉积反应的交换电流,计算值与实验值基本一致。

关键词: 交换电流, 量子电化学, 电化学动力学

Abstract: A theoretically derived expression of the exchange current is presented by using the general expression of thermal activation theory.The calculated values of the exchange current of Fe and Ni electrodeposition are in agreement with the experimental ones.

Key words: Exchange current, Quantum electrochemistry, Electrochemical kinetics

TrendMD:

张遴绍. 量子电化学的交换电流表达式. 高等学校化学学报, 1992, 13(6): 798.

ZHANG Lin-shao . An Expression of Quantum Electrochemistry for Exchange Current. Chem. J. Chinese Universities, 1992, 13(6): 798.