N-异丙基-S-丙基-N′-取代-N′-苯磺酰基硫(醇)代磷酰二胺酯类化合物的研究

高等学校化学学报 ›› 1992, Vol. 13 ›› Issue (2): 191.

N-异丙基-S-丙基-N′-取代-N′-苯磺酰基硫(醇)代磷酰二胺酯类化合物的研究

赖鹏翔¹, 王惠林², 陈茹玉², 刘安西², 徐建华²

1. 山东大学威海分校化学系, 威海, 264200;
2. 南开大学元素有机化学研究所、生物系

收稿日期:1991-01-04 出版日期:1992-02-24 发布日期:1992-02-24
通讯作者: 赖鹏翔

Studies on N-Isopropyl-S-Propyl-N'-Substituent-N'-Benzenesulfonyl Phosphorothlodiamidoates

LAI Peng-xiang¹, WANG Hui-lin², CHEN Ru-yu², LIU An-xi², XU Jian-hua²

1. Dept, of Chem., Shandong Univ. at Weihai, Weihai, 264200;
2. The Rese. Inst. of Elemento-Organic Chem. , Dept. of Biology, Nankai Univ.

Received:1991-01-04 Online:1992-02-24 Published:1992-02-24

摘要/Abstract

摘要： 合成20种新的N-异丙基-S-丙基-N′-取代-N′-苯磺酰基硫(醇)代磷酰二胺酯化合物Ⅰ、Ⅱ。合成Ⅰ时,还分离出3种新的环状磷酰二胺酯内酯化合物Ⅲ,经¹HNMR、元素分析及MS证明了它们的结构。初步电生理测试表明,Ⅰ、Ⅱ类化合物对果蝇幼虫种经通道具有较好的阻断作用。

关键词: S-丙基磷酰二氯, 苯磺酰基硫(醇)代磷酰二胺酯, 生物测试

Abstract: Twenty new N-isopropyl-S-propyl-N'-substitutent-N '-benzene sulfonyl phospho-rothiodiamidoates Ⅰ,Ⅱ were synthesized; a cyclo phosphorodiamidoates (Ⅲ) formed as the byproduct during the reaction; their structures were confirmed by ¹H NMR, elemental analysis or MS, the preliminary bioassay shows that these new compounds have a remarkable insecticidal ac-tivitives.

Key words: S-Propylphosphoryldichloride, Benzenesulfonyl phosphorothiodiamidoate, Bioassay

TrendMD:

赖鹏翔, 王惠林, 陈茹玉, 刘安西, 徐建华. N-异丙基-S-丙基-N′-取代-N′-苯磺酰基硫(醇)代磷酰二胺酯类化合物的研究. 高等学校化学学报, 1992, 13(2): 191.

LAI Peng-xiang, WANG Hui-lin, CHEN Ru-yu, LIU An-xi, XU Jian-hua. Studies on N-Isopropyl-S-Propyl-N'-Substituent-N'-Benzenesulfonyl Phosphorothlodiamidoates. Chem. J. Chinese Universities, 1992, 13(2): 191.